You may not be able to eject (or unmount) a volume--a disk or partition--after sending a file in iChat.
Symptom
When you try to eject a disk, an alert box with this message appears :
After this occurs, you cannot eject the volume as you normally would.
Solution
This occurs after sending another iChat user a file stored on a volume other than the startup disk. To prevent the issue, copy the file to the Mac OS X startup disk before sending the file with iChat.
This document will be updated when more information is available.