When you select the "Synchronize with .Mac" checkbox in the .Mac pane in System Preferences and attempt to sync, you may receive an alert message that says:
If this happens, you may also notice that when you click "Register This Computer," your computer won't get registered.
This can occur if your computer name or long Mac OS X user name contains an ampersand (&). To resolve this issue, either update to Mac OS X 10.4.1 or later, or change your computer name or long user name so that it doesn't contain an ampersand.
To update Mac OS X, either use the Software Update pane of System Preferences, or find the latest update on the Apple Support Downloads page.
If you choose to change your name, there are a couple of places to check to make sure there's no ampersand in the name: