For best results when creating long movies (over 20 minutes), record footage using 16-bit audio. Recording with 12-bit audio may result in a gradual loss of audio-video synchronization. Check the manual that came with your DV camcorder to find out how to set the audio format.
If you have already created a project with 12-bit audio, you may be able to export the project to QuickTime as follows:
This includes versions of iMovie for Mac OS X and Mac OS 9.
Related document
42974: "iMovie: Improving audio and video synchronization"